Product ID:SULFANILAMIDE, S5210, SU134
MSDS Date:09/26/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLLBZ

Emergency Phone: 310-516-8000

Info Phone: 310-516-8000

Preparer: E. BRULL

Cage: 63415

Telephone: 310-516-8000

Cage: JO675

SULFANILAMIDE

CAS: 63-74-1

RTECS: WO8400000

ACGIH TLV: TWA 1 MG/M3 (1995)

LD50 LC50 Mixture:LD50 (ORAL, RAT): 3900 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SLIGHTLY DANGEROUS TO DANGEROUS
IN CASE OF SKIN CONTACT (IRRITANT), OF EYE CONTACT (IRRITANT), OF
INGESTION, OF INHALATION. CORROSIVE TO EYES AND SKIN. THE AMOUNT OF
TISSUE DAMAGE DEPENDS ON LE NGTH OF CONTACT. EYE CONTACT CAN RESULT
IN CORNEAL DAMAGE OR BLINDNESS. SKIN CONTACT CAN PRODUCE
INFLAMMATION AND BLISTERING. INHALATION OF DUST WILL PRODUCE
IRRITATION TO GASTRO-INTESTINAL OR RESPIRA TORY TRACT CHARACTERIZED
BY BURNING, SNEEZING AND COUGHING. SEVERE OVER-EXPOSURE CAN PRODUCE
LUNG DAMAGE, CHOKING, UNCONSCIOUSNESS OR DEATH. CAN BE FATAL IF
INHALED OR INGESTED. THIS PRODUCT MAY IRRIT ATE EYES AND SKIN (EFTS
OF OVEREXPOS)
Effects of Overexposure:HEALTH HAZARD (CONT'D): UPON CONTACT. CHRONIC:
REPEATED EXPOSURE OF THE EYES TO LOW LEVEL OF DUST CAN PRODUCE
IRRITATION. REPEATED SKIN EXPOSURE CAN PRODUCE LOCAL SKIN
DESTRUCTION OR DERMATITIS. REPE ATED INHALATION OF DUST CAN PRODUCE
VARYING DEGREE OF RESPIRATORY IRRITATION OR LUNG DAMAGE. REPEATED
EXPOSURE TO HIGHLY TOXIC MATERIAL MAY PRODUCE GENERAL DETERIORATION
OF HEALTH BY AN ACCUMULATION I N ONE OR MANY HUMAN ORGANS.

First Aid:EYE: CHECK FOR & REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH
EYES WITH WATER FOR AT LEAST 15 MINUTES, KEEPING EYELIDS OPEN. COLD
WATER MAY BE USED. DO NOT USE AN EYE OINTMENT. SEEK MEDICAL
ATTENTION. SKIN: IF THE CHEMICAL GOT ON CLOTHED PORTION OF THE
BODY, REMOVE CONTAMINATED CLOTHES AS QUICKLY AS POSSIBLE,
PROTECTING YOUR OWN HANDS & BODY. PLACE VICTIM UNDER DELUGE
SHOWER. IF CHEMICAL TOUCH ES VICTIM'S EXPOSED SKIN, SUCH AS HANDS,
GENTLY & THOROUGHLY WASH THE CONTAMINATED SKIN WITH RUNNING WATER &
NON-ABRASIVE SOAP. BE PARTICULARLY CAREFUL TO CLEAN FOLDS,
CREVICES, CREASES & GROIN. IF I RRITATION PERSISTS, SEEK
(ECOLOGICAL).

Flash Point:NOT AVAILABLE.
Autoignition Temp:Autoignition Temp Text:N/AV.
Lower Limits:N/AVAILABLE
Upper Limits:N/AVAILABLE
Extinguishing Media:SMALL FIRE: USE DRY CHEMICALS, CO2, WATER SPRAY, OR
FOAM. LARGE FIRE: USE WATER SPRAY, FOG, OR FOAM. DO NOT USE WATER
JET.
Fire Fighting Procedures:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . COMBUSTIBLE. PRODUCTS OF
COMBUSTION: CARBON OXIDES (CO, CO2), NITROGEN OXIDES (NO, NO2).
Unusual Fire/Explosion Hazard:NO SPECIFIC INFORMATION IS AVAILABLE IN
MANUFACTURER'S DATABASE REGARDING THE FLAMMABILITY OR RISK OF
EXPLOSION OF THIS PRODUCT IN THE PRESENCE OF VARIOUS MATERIALS.
RISK OF EXPLOSION OF PRODUCT IN P RESENCE OF MECHANICAL IMPACT OR
STATIC DISCHARGE: NOT AVAILABLE.

Spill Release Procedures:SMALL SPILL: USE APPROPRIATE TOOLS TO PUT
SPILLED SOLID IN CONVENIENT WASTE DISPOSAL CONTAINER. LARGE SPILL:
CORROSIVE SOLID. POISONOUS SOLID. STOP LEAK IF WITHOUT RISK. DO NOT
GET WATER INSIDE CONTAI NER. DO NOT TOUCH SPILLED MATERIAL. USE
WATER SPRAY TO REDUCE VAPORS. PREVENT ENTRY INTO SEWERS, BASEMENTS,
CONFINED AREAS; DIKE IF NEEDED. ELIMINATE ALL SOURCES OF IGNITION.
CALL FOR (OTHER INFO)

Handling and Storage Precautions:KEEP LOCKED UP. KEEP CONTAINER DRY.
KEEP AWAY FROM HEAT & SOURCES OF IGNITION. EMPTY CONTAINERS POSE
FIRE RISK, EVAPORATE RESIDUE UNDER A FUME HOOD. GROUND ALL
EQUIPMENT CONTAINING MATERIAL. DO NOT I NGEST. DO NOT BREATHE DUST.
NEVER ADD WATER TO THIS PRODUCT. IN CASE OF INSUFFICIENT (OTHER
PREC)
Other Precautions:HNDLG/STOR (CONT'D): VENTILATION, WEAR SUITABLE
RESPIRATORY EQUIPMENT. IF INGESTED, SEEK MEDICAL ADVICE & SHOW
CONTAINER OR LABEL. AVOID CONTACT WITH SKIN & EYES. KEEP CONTAINER
DRY. KEEP IN A COOL P LACE. GROUND ALL EQUIPMENT CONTAINING
MATERIAL. CORROSIVE MATERIALS SHOULD BE KEPT IN SEPARATE STORA GE
CABINET OR ROOM.

Respiratory Protection:VAPOR & DUST RESPIRATOR: BE SURE TO USE A NIOSH
APPROVED RESPIRATOR OR EQUIVALENT. WEAR APPROPRIATE RESPIRATOR WHEN
VENTILATION IS INADEQUATE. IN CASE OF LARGE SPILL WEAR A SELF
CONTAINED BREATHING AP PARATUS TO AVOID INHALATION OF PRODUCT.
EXPOSURE LIMITS: TWA:1 MG/M3 (ACGIH, 1995). CONSULST LOCAL
AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. (SUPP SAFETY)
Protective Gloves:IMPERVIOUS GLOVES . .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . SYNTHETIC APRON.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSING.
Supplemental Safety and Health
VENTILATION (CONT'D): IF USER OPERATIONS GENERATE DUST, FUME, OR MIST,
USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT. SYNONYM: 4-AMINOBENZENESULFONAMIDE.

Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:=165.5C, 329.9F
Vapor Pres:NOT AVAILABLE.
Vapor Density:N/AVAIL
Spec Gravity:1.08 (WATER=1).
pH:NOT AVAILABLE.
Solubility in Water:VERY SLIGHT IN COLD WATER
Appearance and Odor:SOLID. ODOR, TASTE, COLOR, AND ODOR THRESHOLD: NOT
AVAILABLE.
Percent Volatiles by Volume:N/AVAILABLE

Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFORMATION IS AVAILABLE IN MANUFACTURER'S DATABASE
REGARDING THE REACTIVITY OF THIS MATERIAL IN PRESENCE OF VARIOUS
OTHER MATERIALS. CORROSIVITY: NON-CORROSIVE IN PRESENCE OF GLASS.
Stability Condition to Avoid:INSTABILITY TEMPERATURE: NOT AVAILABLE.
CONDITONS OF INSTABILITY: NO ADDITIONAL REMARK.

Waste Disposal Methods:DISPOSE IN ACCORDANCE TO ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS . RECYCLE TO PROCESS, IF POSSIBLE.
CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES.

Toxicological Information:SULFANIMIDE: ORAL (LD50): ACUTE: 3900 MG/KG
(RAT); 3000 MG/KG (MOUSE). VAPOR (LC50): ACUTE: 510 PPM (RAT)
(1HOUR). TOXICITY TO ANIMALS: WARNING: THESE LC50 VALUES ARE
ESTIMATED ON BASIS OF A 4-HOUR EX POSURE: ACUTE ORAL TOXICITY(LD50)
3000 MG/KG (MOUSE). ACUTE TOXICITY OF VAPOR (LC50):255 PPM (RAT).
CHRONIC EFFECTS ON HUMANS: TOXICITY OF PRODUCT ON REPRODUCTIVE
SYSTEM: NOT AVAIL. CARCINOGENIC, MUT AGENIC, TERATOGENIC EFFECTS:
NOT AVAIL. SPECIAL REMARKS ON CHRONIC EFFECTS ON HUMANS: PASSES
THROUGH THE PLACENTA, EXCRETED IN MATERNAL MILK. OTHER TOXIC
EFFECTS ON HUMANS: SLIGHTLY DANGEROUS IN CASE OF SKIN CONTACT
(OTHER INFORMATION)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY, BOD5 AND COD: NOT AVAILABLE. PRODUCTS OF
BIODEGRADATION: CARBON OXIDES (CO, CO2), NITROGEN OXIDES (NO,
NO2...). TOXICITY OF PRODUCTS: THE PRODUCTS OF DEGRADATION ARE MORE
TOXIC. FIRST AI D (CONT'D): MEDICAL ATTENTION. SERIOUS SKIN
CONTACT: WASH WITH A DISINFECTANT SOAP & COVER CONTAMINATED SKIN
WITH AN ANTI-BACTERIAL CREAM. SEEK IMMEDIATE MEDICAL ATTENTION.
INHALATION: ALLOW VICTIM TO REST IN A WELL-VENTILATED AREA. SEEK
IMMEDIATE MEDICAL ATTENTION. SERIOUS INHALATION: EVACUATE VICTIM TO
A SAFE AREA AS SOON AS POSSIBLE. LOOSEN TIGHT CLOTHING SUCH AS
COLLAR, TIE, BELT OR WAISTBAND. IF BREATHING DIFFICULT,
(TRANSPORT)

Transport Information:DOT CLASSIFICATION: DOT CLASS 8: CORROSIVE SOLID.
ECOLOGICAL (CONT'D): ADMINISTER OXYGEN. IF VICTIM IS NOT
BREATHING, PERFORM MOUTH-MOUTH RESUSCITATION. WARNING: IT MAY BE
DANGEROUS TO THE PERSON P ROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED MATERIAL IS TOXIC, INFECTIOUS OR
CORROSIVE. SEEK IMMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT
INDUCE VOMITING. HAVE CONSCIOUS PERSO N DRINK SEVERAL GLASSES OF
WATER OR MILK. SEEK IMMEDIATE MEDICAL ATTENTION. SERIOUS INGESTION:
DO NOT INDUCE VOMITING. EXAMINE LIPS & MOUTH TO ASCERTAIN WHETHER
TISSUES ARE DAMAGED, A POSSIBLE INDICAT ION THAT TOXIC MATERIAL WAS
(SARA)

SARA Title III Information:SARA 312 AND 313: SULFANILAMIDE IS LISTED.
TRANSPORT (CONT'D): INGESTED; THE ABSENCE OF SUCH SIGNS, HOWEVER,
IS NOT CONCLUSIVE. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE,
BELT OR WAISTBAND. IF THE VICTIM IS NOT BREATHING, PERFORM
MOUTH-TO-MOUTH RESUSCITATION. SEEK IMMEDIATE MEDICAL ATTENTION.
PHYSICAL/CHEMICAL (CONT'D): MOLECULAR WEIGHT: 172.21. CRITICAL
TEMPERATURE, VOLATILITY, WATER/OIL DIS T. COEFF., IONICITY (IN
WATER), DISPERSION PROPERTIES: NOT AVAILABLE.
Federal Regulatory Information:SULFANILAMIDE IS LISTED ON TSCA AND BY
CERCLA. OTHER REGULATIONS: OSHA: HAZARDOUS BY DEFINITION OF HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200). CANADIAN ENVIRONMENTAL
PROTECTION ACT (CEPA): THIS PRODUCT IS ON THE DOMESTIC SUBSTANCES
LIST (DSL) AND IS ACCEPTABLE FOR USE UNDER THE PROVISIONS OF CEPA.
WHMIS (CANADA): WHMIS CLASS D-1A: MATERIAL CAUSING IMMEDIATE AND
SERIOUS TOXIC EFFECTS (VERY T OXIC). DSCL (EEC): R26-VERY TOXIC BY
INHALATION.
State Regulatory Information:SULFANILAMIDE IS LISTED BY THE STATES OF
MASSACHUSETTS AND PENNSYLVANIA. CALIFORNIA PROPOSITION 65 WARNINGS:
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. CHEMICAL INGREDIENT REQUIRING THIS
WARNING: NONE. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR REPRODUCTIVE
HARM. CHEMICAL INGREDIENT REQUIRING THIS WARNING: NONE.